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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本冈山大学
学位：博士
所在单位：化工学院
学科：精细化工. 应用化学
办公地点：大连理工大学西部校区E209
联系方式：13591789942
电子邮箱：jncui@dlut.edu.cn
One step from nitro to oxime: a convenient preparation of unsaturated oximes by the reduction of the corresponding vinylnitro compounds
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论文类型：期刊论文
发表时间：2009-12-12
发表刊物：TETRAHEDRON
收录刊物：SCIE、Scopus
卷号：65
期号：50
页面范围：10377-10382
ISSN号：0040-4020
摘要：A series of novel unsaturated oximes were conveniently prepared from the corresponding vinylnitro compounds by reduction with SnCl(2)center dot 2H(2)O. The structures of the oximes were characterized by (1)H and (13)C NMR, IR and HRMS, and X-ray crystallography analysis of 1-(6-chloro-pyridin-3-ylmethyl)-4,5-dihydro-1H-imidazole-2-carbaldehyde oxime 2a reveals that, the hydroxyl group is arranged in a trans configuration. Some evidences from a brief investigation suggest that these oximes seem to be formed by reduction of the aci form of nitro aliphatic compounds. (C) 2009 Elsevier Ltd. All rights reserved.