王加升

个人信息Personal Information

副教授

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工海洋与生命学院

学科:应用化学. 化学工程

办公地点:大连理工大学D01-309

电子邮箱:jswang@dlut.edu.cn

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The effect of the support structure on catalytic activity: a case study on hollow and solid MoO3/SiO2

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论文类型:期刊论文

发表时间:2016-01-01

发表刊物:RSC ADVANCES

收录刊物:SCIE、EI

卷号:6

期号:3

页面范围:2374-2378

ISSN号:2046-2069

摘要:Hollow and solid silica nanospheres inlaid with multiple MoO3 nanoclusters are obtained by a reverse microemulsion method. Characterization is carried out based on transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma-optical emission spectrometry (ICP-OES) and N-2 sorption measurements. Their catalytic activity towards acetalization of benzaldehyde was compared. The results showed that the hollow nanocomposite outperformed the solid counterpart. The enhancement of the hollow structure can be attributed to its bigger surface area, shorter pore channels and thus less travelling blockage.