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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：化学工艺. 功能材料化学与化工. 无机化学
办公地点：大连理工大学西部校区化工综合楼D401
联系方式：0411-84986067（办公室） junweiye@dlut.edu.cn
电子邮箱：junweiye@dlut.edu.cn
A novel three-dimensional cadmium(II) coordination polymer constructed from dinuclear molecular building block, syntheses, structure and photoluminescence property
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论文类型：期刊论文
发表时间：2009-02-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：12
期号：2
页面范围：72-75
ISSN号：1387-7003
关键字：Coordination polymer; Cadmium(II); Dinuclear building block; Photoluminescence
摘要：A novel cadmium(II) coordination polymer, [Cd(2)(pzdc)(2)(4,4'-bpy)(2)]center dot 4H(2)O (1) (H(2)pzdc = pyrazine-2,3-dicarboxylic acid; 4,4'-bpy=4,4'-bipyridine), has been synthesized by hydrothermal reaction of Cd(OAC)(2), H(2)pzdc and 4,4'-bpy. Single-crystal X-ray diffraction analysis reveals that 1 constructed from dinuclear building blocks has a three-dimensional (3-D) structure with rob topology. Fluorescent measurement of 1 exhibits strong blue-green emission in the solid state at room temperature, and its framework possess remarkable thermal stability. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.