|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：化学工艺. 功能材料化学与化工. 无机化学
办公地点：大连理工大学西部校区化工综合楼D401
联系方式：0411-84986067（办公室） junweiye@dlut.edu.cn
电子邮箱：junweiye@dlut.edu.cn
A hemidirected 1-D coordination polymer [Pb-2(H2O)(2)(HBTC)(2)] center dot 3H(2)O extended in holodirected 3-D by weak Pb-O interactions
点击次数：
论文类型：期刊论文
发表时间：2007-12-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE、Scopus
卷号：10
期号：12
页面范围：1534-1536
ISSN号：1387-7003
关键字：Pb(II); 1,3,5-Benzenetricarboxylic acid; double-chain; hemidirected; holodirected
摘要：A new complex, [Pb-2(H2O)(2)(HBTC)(2)]center dot 3H(2)O (H3BTC = 1,3,5-Benzenetricarboxylic acid) (1), has been synthesized under hydrothermal condition. The single-crystal analysis shows that 1 consists of 1-D double-chains with Pb(II) six-coordinated by three H3BTC and one H2O molecule with the Pb-O bond distances in the range of 2.56-2.76 angstrom. When the Pb-O bonding limit extends from 2.76 to 2.90 angstrom, the potential weak bonds of Pb-0 can be found and the coordination number of Pb will increase from six to nine. As a result, the coordination geometry of Pb(II) transforms from hemidirected to holodirected and an infinite 3-D framework is obtained by the connection of the double-chains. The IR spectrum and the TGA-DTA curve of 1 are also reported in this paper. (C) 2007 Elsevier B.V. All rights reserved.