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论文类型：期刊论文

发表时间：2017-04-05

发表刊物：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录刊物：SCIE、EI

卷号：56

期号：13

页面范围：3733-3739

ISSN号：0888-5885

摘要：We investigated the solubilization effect of a supercritical carbon dioxide microemulsion based on LS-mn (LS-36, LS-45, and LS-54) surfactants for 1-butyl-3-methyl-imidazolium tetrafluoroborate ([Bmim][BF4]) as well as the influencing factors by analyzing the cloud point pressure (CPP) curves, which served as a function Of dissolved IL concentration. Results show that increased water content (W-0) could enhance [Bmim][BF4] dissolution. Under the same conditions, microemulsion systems consisting of LS-54, LS-45, and LS-36 have the gradually decreased the dissolving capacity for [Bmim][BF4]. However, variation of the surfactant concentration has little influence on dissolving [Bmim][BF4]. In addition, introducing appropriate amounts of ethanol could, decrease the CPP of the system, which did not bring significant enhancement oh [Bmim][BF4] dissolution. Molecular dynamics (MD) simulation was implemented to give an insight about the microstructure and prove the formation of the microemulsion: