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论文类型：期刊论文

发表时间：2003-01-01

发表刊物：SEPARATION SCIENCE AND TECHNOLOGY

收录刊物：SCIE、EI

卷号：38

期号：16

页面范围：4041-4055

ISSN号：0149-6395

关键字：simulation; supercritical fluid extraction; Hippophae rhamnoides L. seed

摘要：Modeling of supercritical CO2 extraction of Hippophae rhamnoides L. seed oil was studied at 15 to 30 MPa and 30 to 45degreesC. Four mean Hippophae rhamnoides L. particle sizes raging from 0.4 to 1.0 mm were tested. CO2 flow rate ranged between 0.05 and 0.2 m(3) h(-1). A new method that can be used for the simulation of SCFE process was presented. The model was based on differential mass balances along the extraction bed. The equilibrium between the solid and the fluid phase appeared to be the controlling step during the extraction fast period. By a series of transforms and derivatives, the explicit expression of the oil yield, q(z,t), was obtained. It can be used for the SUE process simulation. In this model, only one adjustable parameter was used: the equilibrium constant between the solvent and the free solute phase, K. A fairly good fitting of the experimental data was obtained by setting K = 10. The Hippophae rhamnoides L. seed oil extraction process was modeled as a desorption process from the seed matter plus a small mass-transfer resistance.