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论文类型：期刊论文

发表时间：2012-11-01

发表刊物：SCIENCE OF ADVANCED MATERIALS

收录刊物：SCIE、Scopus

卷号：4

期号：11

页面范围：1148-1153

ISSN号：1947-2935

关键字：ZnO Quantum Dots; Two-Phase Route; Surface Modification; Dispersity

摘要：A two-phase system methanol-hexane is developed in the current work. These colloidal ZnO quantum dots (QDs) emission with yellow prepared by a traditional sol gel approach can realize surface modification with oleic acid (OA) via the two-phase route. The Pearson's Hard and Soft [Lewis] Acid and Base Principle together with the effect of microemulsion determines the OA capping on ZnO QDs. These ZnO QDs after surface modification with OA are highly stable in structure and optical properties as well as dispersity. This two-phase route successfully inhibits ZnO QDs from turning to acetate anion intercalated Zn based hydroxyl double salts. The visible emission intensity of these ZnO QDs after surface modification is unchanged as time went on. The dispersity of these ZnO QDs after surface modification is improved greatly and these ZnO QDs after surface modification can be stable in non-polar solvents for a long time.