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论文类型：期刊论文

发表时间：2015-07-06

发表刊物：INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

收录刊物：SCIE、EI

卷号：40

期号：25

页面范围：7983-7990

ISSN号：0360-3199

关键字：Steam reforming; Biomass tar; Hydrogen production; NiO/ceramic foam catalyst

摘要：In this study, the catalytic steam reforming of biomass tar for hydrogen production was carried out in a fixed-bed reactor with NiO/ceramic foam catalyst. The ceramic foam used as catalyst carrier was a three-dimensional porous material with high porosity and high specific heat capacity. The effects of reaction temperature, steam to carbon ratio (S/C) and equivalence ratio (ER) on gas quality parameters were investigated. And the fresh, coked and regenerated NiO/ceramic foam catalysts were characterized by SEM and XRD analyses. It was found that, when the temperatures varied from 500 to 900 degrees C and S/C ratio from 0 to 4, H-2 yields were in the range of 28.29-105.28 g H-2/kg tar. With increasing ERs, the concentrations of H-2 decreased from 63.13 to 18.96%. SEM and XRD analyses showed that the catalyst was in situ activated by reducing nickel oxide to the active nickel metal during a reducing atmosphere in steam reforming process. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.