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论文类型：期刊论文

发表时间：2012-06-01

发表刊物：INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

收录刊物：SCIE、EI

卷号：37

期号：12

页面范围：9610-9618

ISSN号：0360-3199

关键字：Biomass; Hydrogen production; Gasification; Kinetics

摘要：In the present study, an updraft biomass gasifier combined with a porous ceramic reformer was used to carry out the gasification reforming experiments for hydrogen-rich gas production. The effects of reactor temperature, equivalence ratio (ER) and gasifying agents on the gas yields were investigated. The results indicated that the ratio of CO/CO2 presented a clear increasing trend, and hydrogen yield increased from 33.17 to 44.26 g H-2/kg biomass with the reactor temperature increase, The H-2 concentration of production gas in oxygen gasification (oxygen as gasifying agent) was much higher than that in air gasification (air as gasifying agent). The ER values at maximum gas yield were found at ER = 0.22 in air gasification and at 0.05 in oxygen gasification, respectively. The hydrogen yields in air and oxygen gasification varied in the range of 25.05-29.58 and 25.68-51.29 g H-2/kg biomass, respectively. Isothermal standard reduced time plots (RTPs) were employed to determine the best-fit kinetic model of large weight biomass air gasification isothermal thermogravimetric, and the relevant kinetic parameters corresponding to the air gasification were evaluated by isothermal kinetic analysis. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.