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论文类型：期刊论文

发表时间：2010-07-15

发表刊物：JOURNAL OF HAZARDOUS MATERIALS

收录刊物：SCIE、EI、PubMed

卷号：179

期号：1-3

页面范围：911-917

ISSN号：0304-3894

关键字：PCB waste pyrolysis oil; Resource utilization; CNTs; Porous carbons

摘要：The possibility and feasibility of using pyrolysis oil from printed circuit board (PCB) waste as a precursor for advanced carbonaceous materials is presented. The PCB waste was first pyrolyzed in a laboratory scale fixed bed reactor at 600 degrees C to prepare pyrolysis oil. The analysis of pyrolysis oil by gas chromatography-mass spectroscopy indicated that it contained a very high proportion of phenol and phenol derivatives. It was then polymerized in formaldehyde solution to synthesize pyrolysis oil-based resin which was used as a precursor to prepare carbon nanotubes (CNTs) and porous carbons. Scanning electron microscopy and transmission microscopy investigation showed that the resulting CNTs had hollow cores with outer diameter of similar to 338 nm and wall thickness of similar to 86 nm and most of them were filled with metal nanoparticles or nanorods. X-ray diffraction reveals that CNTs have an amorphous structure. Nitrogen adsorption isotherm analysis indicated the prepared porous carbons had a Brunauer-Emmett-Teller surface area of 1214 m(2)/g. The mechanism of the formation of the CNTs and porous carbons was discussed. (C) 2010 Elsevier B.V. All rights reserved.