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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：工业催化. 能源化工. 物理化学
办公地点：西校区化工实验楼B525
电子邮箱：liganghg@dlut.edu.cn
Highly efficient epoxidation of propylene to propylene oxide over TS-1 using urea plus hydrogen peroxide as oxidizing agent
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论文类型：期刊论文
发表时间：2008-04-25
发表刊物：JOURNAL OF CATALYSIS
收录刊物：SCIE、EI
卷号：255
期号：2
页面范围：343-346
ISSN号：0021-9517
关键字：epoxidation; propylene; propylene oxide; urea; hydrogen peroxide; titanium silicate-1; electron paramagnetic resonance
摘要：We compared the efficacies of urea + hydrogen peroxide (U+HP) and hydrogen peroxide (HP) as an oxidizing agent in the epoxidation of propylene catalyzed by a titanium silicate-1 (TS-1) molecular sieve. The TS-1 catalyst exhibited good performance and stability in the TS-1/(U+HP) system. EPR results showed that more active Ti-superoxo species led to better performance of TS-1 in the TS-1/(U+HP) system than in the TS-1/HP system. (c) 2008 Elsevier Inc. All rights reserved.