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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：男
毕业院校：中科院长春应用化学研究所
学位：博士
所在单位：化工学院
办公地点：大连理工大学西部校区精细化工国家重点实验室
联系方式：0411-84986251
电子邮箱：lcchen@dlut.edu.cn
Catalyst-Free One-Pot Synthesis of Unsymmetrical Five- and Six-Membered Sulfur-Annulated Heterocyclic Perylene Diimides for Electron-Transporting Property
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论文类型：期刊论文
发表时间：2019-07-19
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、PubMed
卷号：21
期号：14
页面范围：5529-5532
ISSN号：1523-7060
摘要：A novel unsymmetrical five- and six-membered sulfur-annulated heterocyclic perylene diimides (PDI) derivative was obtained by a one-pot and catalyst-free synthesis in a high yield. The unsymmetrical PDI exhibits a noteworthy bathochromic shift absorption of up to 700 nm and a low-lying lowest unoccupied molecular orbital level of -3.99 eV. The compound owns a complete planar structure and a high electron mobility of 4.8 x 10(-3) cm(2) V-1 s(-1) in solution-processable top-gate/bottom-contact organic field-effect transistor device.