凌铮

个人信息Personal Information

副教授

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:能源与动力学院

学科:能源与环境工程

办公地点:能动学院811

联系方式:zling@dlut.edu.cn

电子邮箱:zling@dlut.edu.cn

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Carbon foams made of in situ produced carbon nanocapsules and the use as a catalyst for oxidative dehydrogenation of ethylbenzene

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论文类型:期刊论文

发表时间:2013-08-01

发表刊物:CARBON

收录刊物:SCIE、EI

卷号:60

页面范围:514-522

ISSN号:0008-6223

摘要:Carbon foams (CFoams) were made by combining a hard template with a catalytic graphitization method, in which polyurethane foam is used as a sacrificial template, polyamic acid is used as carbon source and Ni is used as catalyst. The cell walls of CFoams are made of in situ self-assembled carbon nanocapsules (CNCs) with diameters of 30-80 nm. The open cells of the CFoams are, on average, 500 mu m in diameter, and the cell walls are mesoporous. Thermogravimetric analysis reveals that CNCs account for about 85 wt.% of the CFoams (exclusive of the Ni). The CFoams show high activity and selectivity in the reaction of oxidative dehydrogenation of ethylbenzene to styrene. (C) 2013 Elsevier Ltd. All rights reserved.