个人信息Personal Information
副教授
硕士生导师
性别:女
毕业院校:大连理工大学
学位:博士
所在单位:化学学院
学科:有机化学
电子邮箱:liufengyu@dlut.edu.cn
Novel fluorescent pH sensors based on intramolecular hydrogen bonding ability of naphthalimide
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论文类型:期刊论文
发表时间:2004-08-05
发表刊物:ORGANIC LETTERS
收录刊物:SCIE、PubMed
卷号:6
期号:16
页面范围:2757-2760
ISSN号:1523-7060
摘要:4-Piperidine-naphthalimide derivatives containing potential acceptors for hydrogen bonding were synthesized, and their fluorescence properties were examined. Some of the compounds with a 2-imino-oxalidin (thiazolidin) side chain at the imide moiety exhibit a strong fluorescence quench and some red shift in weakly acidic conditions, caused by the formation of an intramolecular hydrogen bond. Their pK(a), values were estimated to be about 6.4-7.5. The results showed that these compounds could serve as novel fluorescent pH sensors for further application.