刘凤玉

个人信息Personal Information

副教授

硕士生导师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化学学院

学科:有机化学

电子邮箱:liufengyu@dlut.edu.cn

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Revisit of a series of ICT fluorophores: skeletal characterization, structural modification, and spectroscopic behavior

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论文类型:期刊论文

发表时间:2014-09-02

发表刊物:TETRAHEDRON

收录刊物:SCIE、Scopus

卷号:70

期号:35

页面范围:5872-5877

ISSN号:0040-4020

关键字:ICT fluorophore; Skeletal characterization; Oxidative SNArH; 2D NMR; X-ray diffraction

摘要:We have revisited the synthesis of a series of ICT fluorophores, which were reported to have a core structure of 8-oxo-8H-acenaphtho[1,2-b]pyrrol-9-carbonitrile. However, based on the 2D NMR and X-ray diffraction analysis, their core structure was corrected as 1-oxo-1H-phenalene-2,3-dicarbonitrile (1). Compound 1 shows a highly electron-deficient nature and can easily undergo oxidative SNArH reaction on the naphthyl ring to produce a series of novel ICT fluorophores. The regioselectivity of this substitution reaction was studied by introduction of representative nucleophiles. Moreover, due to the strong rigidity and efficient ICT nature, the obtained fluorescent dyes display very good spectroscopic properties even in an aqueous environment. (C) 2014 Elsevier Ltd. All rights reserved.