论文成果
O-atom effect on the dynamic balance between redox-induced viologen derivative radical and its dimer modulated by cucurbit[8]uril
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- 论文类型：期刊论文
- 发表时间：2013-07-01
- 发表刊物：SUPRAMOLECULAR CHEMISTRY
- 收录刊物：SCIE
- 文献类型：J
- 卷号：25
- 期号：7
- 页面范围：401-408
- ISSN号：1061-0278
- 关键字：cucurbit[8]uril; host-guest complexes; radical dimer; self-assembly;
apparent dimerisation constant
- 摘要：A series of viologen derivatives were synthesised, which can form stable 1:1 inclusion complexes with cucurbit[8]uril (CB[8]) in aqueous solution. The one-electron-reduced viologen radical cations and its dimerisation encapsulated into CB[8] were studied spectroscopically. The monomer-dimer dynamic balance would exist in the molecules containing O-atom, while the molecules without O-atom retain the form of radical monomer in CB[8] cavity. The result demonstrated that the dynamic balance of radical monomer and dimer of these complexes can be modulated by CB[8].
