刘凤玉
个人信息Personal Information
副教授
硕士生导师
性别:女
毕业院校:大连理工大学
学位:博士
所在单位:化学学院
学科:有机化学
电子邮箱:liufengyu@dlut.edu.cn
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Redox-induced Ru(bpy)(3)(2+) -methylviologen radical formation and its dimerization in cucurbit[8]uril
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论文类型:期刊论文
发表时间:2011-01-14
发表刊物:PHYSICAL CHEMISTRY CHEMICAL PHYSICS
收录刊物:PubMed、SCIE、Scopus
卷号:13
期号:2
页面范围:570-575
ISSN号:1463-9076
摘要:A redox-induced radical Ru(bpy)(3)(2+)-(CH2)(n)-MV+center dot (n = 4, 7) and its dimerization in cucurbit[8] uril (CB[8]) have been observed concomitantly in aqueous solution, which depends heavily on the length of the carbon chain linkage, in the case of n = 4, the characteristic pattern for the radical dimer is predominating, while that for the radical becomes dominated for n = 7.