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Reductive transformation of p-nitrotoluene by a new iron-fly ash packing

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Indexed by:Journal Papers

Date of Publication:2015-11-01

Journal:JOURNAL OF ENVIRONMENTAL SCIENCES

Included Journals:SCIE、EI、PubMed、ISTIC

Volume:37

Page Number:31-36

ISSN No.:1001-0742

Key Words:New iron-fly ash packing; Reactor; Reductive transformation; p-Nitrotoluene

Abstract:A new iron-fly ash packing was studied for reductive transformation of p-nitrotoluene. The packing was made of iron, fly ash and kaolin with the mass ratio of 36:7:2. A reactor was designed to investigate the long-term performance of the packing. The results showed that the reduction of p-nitrotoluene increased with decreasing pH, because the reduction potential of reaction increased with the concentration of H+. The pH was one of the key factors impacting the reductive transformation of p-nitrotoluene. Comparing iron-activated carbon packing with the new iron-fly ash packing, the reduction efficiencies were respectively 76.61% and 75.36% after 20 days. The reduction efficiency for both was around 50% at 40 days. It was evident that these two kinds of packing had no significant difference in their capability for p-nitrotoluene reductive transformation. Compared with iron-activated carbon, the new iron-fly ash packing had obvious advantages in terms of manufacturing costs and environmental pollution degradation. This study showed that the new iron-fly ash packing had good performance in reductive transformation of nitrotoluene compounds. (C) 2015 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

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