刘民

个人信息Personal Information

副教授

博士生导师

硕士生导师

主要任职:Associate Professor

其他任职:系教工党支部书记

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:工业催化. 能源化工

办公地点:大连理工大学西校区化工实验楼B421

电子邮箱:lium@dlut.edu.cn

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论文成果

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Facile synthesis of size-controlled MIL-100(Fe) with excellent adsorption capacity for methylene blue

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论文类型:期刊论文

发表时间:2015-12-01

发表刊物:CHEMICAL ENGINEERING JOURNAL

收录刊物:SCIE、EI、Scopus

卷号:281

页面范围:360-367

ISSN号:1385-8947

关键字:MOFs; MIL-100(Fe); Particle size; Adsorption; Methylene blue

摘要:In this work, the average particle size of metal organic framework (MOF) MIL-100(Fe) was modulated notably from 100 nm to 20 mu m by changing the valence state of iron in iron sources and the amount of HF during hydrothermal reactions. The sorption capacity of MIL-100(Fe) for methylene blue (MB) increases with the particle size, and the maximum sorption capacity of the largest particles reached 1105 mg/g, much higher than previous reports on MOFs. The high sorption capacity could be attributed to high surface area and suitable pore structure. Additionally, the particle size determined the adsorption rate. The smaller the particle size, the higher the adsorption rate. The adsorption isotherms were adequately fitted with the Langmuir model and the kinetic data were followed by the pseudo-second-order model. Besides, MIL-100(Fe) possessed good recyclability which can be regenerated by washing with ethanol. These results identified that MIL-100(Fe) exhibited great potential for purification of MB wastewater. (C) 2015 Elsevier B.V. All rights reserved.