刘民

个人信息Personal Information

副教授

博士生导师

硕士生导师

主要任职:Associate Professor

其他任职:系教工党支部书记

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:工业催化. 能源化工

办公地点:大连理工大学西校区化工实验楼B421

电子邮箱:lium@dlut.edu.cn

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论文成果

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Templated fabrication of hierarchically porous Fe-Ti bimetallic solid superacid for efficient photochemical oxidation of azo dyes under visible light

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论文类型:期刊论文

发表时间:2014-05-15

发表刊物:CHEMICAL ENGINEERING JOURNAL

收录刊物:SCIE、EI、Scopus

卷号:244

页面范围:296-306

ISSN号:1385-8947

关键字:Hierarchically porous solid superacid; Hydrogen peroxide; Synergetic effect; Photo-induced electrons transfer; Lewis acid site

摘要:A new hierarchically porous solid superacid SO42-/Fe2-xTixO3 was prepared by way of facile citric acid templates and sulfuric acid impregnating strategy. The prepared catalyst exhibited high activity and stability for activation of H2O2 as higher than 90% of organic dyes were decomposed in 30 min at neutral pH under visible light irradiation. UV-vis spectrum and ion chromatography were used to investigate the degradation pathway of dyes. By characterizations, it was found that incorporation of titanium and sulfur had a significant effect on properties and structure of the solid. Large numbers of strong Lewis acid sites were produced on the surface due to cooperative effect of Ti and S, which made significant contributions toward high activity in strong alkaline condition (pH 10.0). Meanwhile, the transition metal doping and oxygen vacancies generation can narrow the band gap of the catalyst and efficiently enhance visible light photocatalytic performance. It was also observed that high catalytic activity can hardly be achieved if acid functionalization or light irradiation was applied individually. This was clearly evidenced that the synergetic effect of acid sites and photo-induced electrons transfer played a crucial role in Fenton reaction, which may be attributed to that the appearance of acid sites (Lewis and Bronsted acidic center) was favorable for the separation of photo-induced electrons and holes and suppressed charge recombination. (C) 2014 Elsevier B.V. All rights reserved.