刘民

个人信息Personal Information

副教授

博士生导师

硕士生导师

主要任职:Associate Professor

其他任职:系教工党支部书记

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:工业催化. 能源化工

办公地点:大连理工大学西校区化工实验楼B421

电子邮箱:lium@dlut.edu.cn

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论文成果

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Effective Hydrolysis of Cellulose into Glucose over Sulfonated Sugar-Derived Carbon in an Ionic Liquid

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论文类型:期刊论文

发表时间:2013-06-19

发表刊物:INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录刊物:SCIE、EI、Scopus

卷号:52

期号:24

页面范围:8167-8173

ISSN号:0888-5885

摘要:Sulfonated sucrose-derived carbon, glucose-derived carbon, and nut shell activated carbon (NSAC) catalysts were prepared and characterized by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). FT-IR and XPS spectra showed that -SO3H groups could be introduced into the carbon precursors after the sulfonation treatment. Higher concentration of -SO3H groups in the sulfonated sucrose-carbon and glucose-carbon most likely accounts for their higher activities compared to sulfonated NSAC. Hydrolysis of microcrystalline cellulose was examined in a common ionic liquid, 1-butyl-3-methylimidazolium chloride ([BMIM]Cl), with the sulfonated carbon catalysts. Maximum yields of glucose (59%) and total products (80%, defined as the sum of glucose, cellobiose, and 5-hydroxymethylfurfural) could be obtained with sulfonated sucrose-carbon at 120 degrees C for 4 h. With a regeneration procedure, the catalyst could be reused.