个人信息Personal Information
副教授
博士生导师
硕士生导师
主要任职:Associate Professor
其他任职:系教工党支部书记
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:工业催化. 能源化工
办公地点:大连理工大学西校区化工实验楼B421
电子邮箱:lium@dlut.edu.cn
Synthesis of Silica Nanotubes with Orientation Controlled Mesopores in Porous Membranes via Interfacial Growth
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论文类型:期刊论文
发表时间:2012-03-27
发表刊物:CHEMISTRY OF MATERIALS
收录刊物:SCIE、EI、Scopus
卷号:24
期号:6
页面范围:1005-1010
ISSN号:0897-4756
关键字:silica nanotube; mesoporous film; mesopore orientation; perpendicular; interfacial growth
摘要:Silica nanotubes with mesopores perforating the wall were synthesized on the channel surface of porous anodic alumina (PAA) or polycarbonate membranes via interfacial growth. Transmission and scanning electron microscopy characterizations indicated that the mesopore orientation can be regulated from perpendicular to the wall to circling the axis when the thickness of the silica nanotube wall increases from about 15 to 40-60 nm, without any modification of the channel surface or external forces, just by optimizing the amount of the tetraethoxysilane confined in the channels of PAA. Mesopores in the silica nanotube wall arrange hexagonally when the diameter of the silica nanotubes is larger than 200 nm.