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论文类型：期刊论文

发表时间：2010-09-01

发表刊物：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录刊物：SCIE、EI、Scopus

卷号：49

期号：17

页面范围：8157-8163

ISSN号：0888-5885

摘要：Several SO3H-functionalized ionic liquids (Fits) were synthesized and their catalytic performances for catechol (CAT) alkylation with tert-butyl alcohol (TBA) were studied theoretically as well as experimentally. Under optimized reaction conditions, the conversion of CAT was 41.5%, and the selectivity for 4-tert-butyl catechol (4-TBC) could reach 97.1%. This electrophilic reaction exhibits a kinetics-dependent character. The higher frontier electron density at the C-4 site, comparatively lower activation energy barrier (E-a), and higher thermodynamic stability all act in concert to make the reaction proceed preferentially toward 4-TBC. The FILs can lead to a much higher CAT conversion and a similar selectivity to 4-TBC compared to a Beta zeolite catalyst. Because the frontier electron density [f(r)(E)] of CAT was not significantly affected by the solvent, the product selectivity rule would not vary, whereas the addition of a solvent with a higher dielectric constant would slow the reaction by increasing E-a, thus resulting in a lower CAT conversion.