个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:化工学院院长、党委副书记
性别:男
毕业院校:北京大学
学位:博士
所在单位:化工学院
学科:无机化学. 应用化学. 精细化工
办公地点:大连理工大学西部校区F208
联系方式:0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/
电子邮箱:liutao@dlut.edu.cn
Coexistence of metamagnetism and single chain magnet behavior in a (Fe2CoII)-Co-III layer compound
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论文类型:期刊论文
发表时间:2016-06-01
发表刊物:SCIENCE CHINA-CHEMISTRY
收录刊物:SCIE、EI、CSCD
卷号:59
期号:6
页面范围:735-739
ISSN号:1674-7291
关键字:double-zigzag chain; metamagnetism; single-chain magnets
摘要:A cyanide-bridged (Fe2CoII)-Co-III double zigzag chain, {[Fe-III(bipy)(CN)(4)](2)Co-II(btab)(2)}(n) [bipy=2,2'-bipyridine, btab=4,4'-(1,3-phenylene)-bis-4H-1,2,4-triazole] (1), was obtained with tetracyanometalate precursors and Co-II ions. The chains were further linked by the ditopic btab ligands to a layer. Magnetic property studies demonstrate that 1 shows both metamagnetism with a critical field H-c=400 Oe and single-chain magnet behavior.