刘涛

个人信息Personal Information

教授

博士生导师

硕士生导师

主要任职:化工学院院长、党委副书记

性别:男

毕业院校:北京大学

学位:博士

所在单位:化工学院

学科:无机化学. 应用化学. 精细化工

办公地点:大连理工大学西部校区F208

联系方式:0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/

电子邮箱:liutao@dlut.edu.cn

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Two cyano-bridged {(Fe4M2II)-M-III}c (M = Fe-II, Co-II) hexanuclear complexes with dominant ferromagnetic interactions

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论文类型:期刊论文

发表时间:2015-07-01

发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS

收录刊物:SCIE、Scopus

卷号:57

页面范围:33-35

ISSN号:1387-7003

关键字:Self-assembly; Cyanide; Hexanuclear; Ferromagnetic

摘要:Two hexanuclear complexes of formula [Fe-III(Tp*)(CN)(3)](4)[Fe-II(tptz)](2) (1), [Fe-III(Tp*)(CN)(3)](4)[Co-II(tptz)](2) (2) [Tp* = hydridotris(3,5-dimethylpyrazolyl)borate, tptz = (2,4,6-tris-(2-pyridyl)1,3,5-triazine] have been synthesized via directional assembly of metallocyanate precursor and metal cationic ions. The magnetic properties characterization indicate that ferromagnetic interactions dominate in the two complexes, resulting in a spin ground state of S = 5 and S = 6, respectively. (C) 2015 Elsevier B.V. All rights reserved.