个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:化工学院院长、党委副书记
性别:男
毕业院校:北京大学
学位:博士
所在单位:化工学院
学科:无机化学. 应用化学. 精细化工
办公地点:大连理工大学西部校区F208
联系方式:0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/
电子邮箱:liutao@dlut.edu.cn
Two cyano-bridged {(Fe4M2II)-M-III}c (M = Fe-II, Co-II) hexanuclear complexes with dominant ferromagnetic interactions
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论文类型:期刊论文
发表时间:2015-07-01
发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物:SCIE、Scopus
卷号:57
页面范围:33-35
ISSN号:1387-7003
关键字:Self-assembly; Cyanide; Hexanuclear; Ferromagnetic
摘要:Two hexanuclear complexes of formula [Fe-III(Tp*)(CN)(3)](4)[Fe-II(tptz)](2) (1), [Fe-III(Tp*)(CN)(3)](4)[Co-II(tptz)](2) (2) [Tp* = hydridotris(3,5-dimethylpyrazolyl)borate, tptz = (2,4,6-tris-(2-pyridyl)1,3,5-triazine] have been synthesized via directional assembly of metallocyanate precursor and metal cationic ions. The magnetic properties characterization indicate that ferromagnetic interactions dominate in the two complexes, resulting in a spin ground state of S = 5 and S = 6, respectively. (C) 2015 Elsevier B.V. All rights reserved.