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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：化工学院院长、党委副书记
性别：男
毕业院校：北京大学
学位：博士
所在单位：化工学院
学科：无机化学. 应用化学. 精细化工
办公地点：大连理工大学西部校区F208
联系方式：0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/
电子邮箱：liutao@dlut.edu.cn
A cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions
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论文类型：期刊论文
发表时间：2015-01-14
发表刊物：DALTON TRANSACTIONS
收录刊物：PubMed、SCIE、Scopus
卷号：44
期号：2
页面范围：464-467
ISSN号：1477-9226
摘要：It is a challenge to synthesize a porous tubular coordination polymer with magnetic properties. Utilizing [Fe-II(bipy)(CN)(4)](2-) (bipy = 2,2'-bipyridine) as the building block to react with Mn2+, we successfully synthesized a cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions. The inner surface of the heterometallic tube is hydrophilic, whereas the outer surface is hydrophobic. The framework is stable up to 320 degrees C and can adsorb N-2 and CO2. The ferromagnetic interactions were transmitted via the diamagnetic N-C-Fe-II-C-N species between Mn2+ ions in the tube.