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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：化工学院院长、党委副书记
性别：男
毕业院校：北京大学
学位：博士
所在单位：化工学院
学科：无机化学. 应用化学. 精细化工
办公地点：大连理工大学西部校区F208
联系方式：0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/
电子邮箱：liutao@dlut.edu.cn
From tetranuclear cluster with single-molecule-magnet behavior to 1D alternating spin-canting chain in a Fe(III)-Mn(III) bimetallic system
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论文类型：期刊论文
发表时间：2014-09-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：47
页面范围：155-158
ISSN号：1387-7003
关键字：Self-assembly; Cyanide; Schiff bases; Building block; Spin-canting; Single-molecule magnets
摘要：A tetranuclear cluster and an alternating zigzag chain were synthesized via rational assembly of the same cyanometalate building blocks with different Mn(III) Schiff bases possessing varying proportions of sterically hindered groups causing steric hindrances. The tetranuclear cluster [(Tp*)Fe(CN)(3)](2)[Mn(salen)](2)center dot H2O [1; [(Tp*) Fe(CN)(3)](-) [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl) borate], salen N,N'-ethylenebis(salicylideneiminato) dianion] was formed with Schiff bases possessing smaller steric hindrances, whereas the one-dimensional alternating zigzag chain {[(Tp*)Fe(CN)(3)Mn(salcyen)]center dot 2CH(3)OH center dot H2O}(n) [2; salcyen = N,N'-(1,2-cyclohexanediylethylene) bis(salicylideneiminato) dianion] was formed with Schiff bases possessing larger steric hindrances. Magnetic measurements revealed that 1 exhibits single-molecule-magnet behavior with dominant ferromagnetic interactions, whereas 2 exhibits spin-canting behavior with dominant antiferromagnetic interactions. (C) 2014 Elsevier B.V. All rights reserved.