个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:化工学院院长、党委副书记
性别:男
毕业院校:北京大学
学位:博士
所在单位:化工学院
学科:无机化学. 应用化学. 精细化工
办公地点:大连理工大学西部校区F208
联系方式:0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/
电子邮箱:liutao@dlut.edu.cn
Synthesis, structure, and magnetic properties of a cyanidebridged Fe(III)-Cu(II) bimetallic double-zigzag chain with slow relaxation of the magnetization
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论文类型:期刊论文
发表时间:2012-06-01
发表刊物:SCIENCE CHINA-CHEMISTRY
收录刊物:SCIE、EI
卷号:55
期号:6
页面范围:1018-1021
ISSN号:1674-7291
关键字:single chain magnet; double-zigzag chain; ferromagnetic coupling
摘要:Using Bu4N[Fe(Tp*)(CN)(3)](-) (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) as the building block to react with Cu-II and N-methylimidazole, we obtained a one-dimensional (1D) heterobimetallic cyano-bridged chain, [Fe(Tp*)(CN)(3)](2)Cu(N-methylimidazole)(2)center dot 2H(2)O (1). The crystal structures and magnetic studies demonstrate that complex 1 exhibits slow relaxation of the magnetization due to strong intrachain ferromagnetic coupling and weak interchain interactions.