个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:化工学院院长、党委副书记
性别:男
毕业院校:北京大学
学位:博士
所在单位:化工学院
学科:无机化学. 应用化学. 精细化工
办公地点:大连理工大学西部校区F208
联系方式:0411-84986296 liutao@dlut.edu.cn https://liutao.dlut.edu.cn/
电子邮箱:liutao@dlut.edu.cn
Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain
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论文类型:期刊论文
发表时间:2012-05-21
发表刊物:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物:SCIE、EI、PubMed、Scopus
卷号:51
期号:21
页面范围:5119-5123
ISSN号:1433-7851
关键字:chain structures; charge transfer; cobalt; iron; magnetic properties
摘要:Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated FeIII2CoII chains of {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2} 2H 2O 2CH3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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