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论文类型：期刊论文

发表时间：2017-11-25

发表刊物：JOURNAL OF ALLOYS AND COMPOUNDS

收录刊物：SCIE、EI

卷号：725

页面范围：1264-1271

ISSN号：0925-8388

关键字：Al-Si-Sn alloy; Rotating magnetic field; Microstructure; Separation; Purification; Synchrotron radiation

摘要：In the present work, the effect of Sn addition on the separation and purification of primary Si from solidification of Al-30Si melt under rotating magnetic field (RMF) was investigated. The results revealed that the as-cast solidification microstructure of ternary Al-30Si-Sn alloy is composed of the primary Si phase, eutectic alpha-Al+Si, and eutectic alpha-Al+beta-Sn structure. The application of RMF can separate the primary Si from solidification of Al-30Si-Sn melt, consequently forming a Si-rich layer on the periphery of the ingot. The atomic fraction of primary Si in Si-rich layer increases with increasing Sn content because the addition of Sn can enlarge the crystallization temperature range of the primary Si phase. The content of non-metallic B in primary Si increases due to the increasing segregation coefficient of B with the increasing Sn content. However, the contents of typical metallic impurities (Fe and Ca) exhibit an opposite trend, which may be attributed to the back-diffusion of impurities suppressed by the addition of Sn. (C) 2017 Elsevier B.V. All rights reserved.