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论文类型：期刊论文

发表时间：2020-01-01

发表刊物：Science Advances

收录刊物：EI

卷号：6

期号：7

摘要：Zeolite nanosheets have shown unprecedented opportunities for a wide range of applications, yet developing facile methods for fabrication of uniform zeolite nanosheets remains a great challenge. Here, a facile approach involving anisotropic etching with an aqueous solution of tetrapropylammonium hydroxide (TPAOH) was developed for preparing uniform high-aspect ratio hierarchical MFI nanosheets. In addition, the mechanism associated with the formation of MFI nanosheets was proposed. In the next step, a dynamic air-liquid interface-assisted self-assembly method and single-mode microwave heating were used for b-oriented MFI nanosheets monolayer deposition and controlled in-plane solution-based epitaxial growth, respectively, ensuring the formation of well-intergrown b-oriented MFI layers with sub-100-nm thickness. Moreover, our study indicated that b-oriented ultrathin MFI layers could be fabricated on diverse substrates demonstrating excellent anticorrosion capacity, ionic sieving properties, and n-/i-butane isomer separation performance. Copyright ? 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).