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论文类型：期刊论文

发表时间：2017-11-01

发表刊物：JOURNAL OF ENERGY CHEMISTRY

收录刊物：SCIE、EI、Scopus

卷号：26

期号：6

页面范围：1140-1146

ISSN号：2095-4956

关键字：In-situ carbonization; Ordered mesoporous carbon; HER

摘要：A binder-free Ir-dispersed ordered mesoporous carbon (Ir-OMC) catalytic electrode has been prepared through a designed in-situ carbonization method, which involves coating resorcinol and formaldehyde mixtures with iridium precursors onto the three-dimensional nickel foam framework, followed by in-situ calcination in N-2 atmosphere at 800 degrees C for 3 h. This electrode shows a large surface area, ordered mesoporous structure and homogeneous distribution of metal nanoparticles. It presents good activity and stability towards hydrogen evolution reaction, which is attributed to the efficient mass and electron transport from the intimate contact among Ir nanoparticles, ordered mesoporous carbon matrix and 3D conductive substrate. We hope that this in-situ carbonization synthetic route can also be applied to design more high-performance catalysts for water splitting, fuel cells and other clean energy devices. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.