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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：中科院金属所
学位：博士
所在单位：化工学院
学科：无机化学
办公地点：大连理工大学化学楼401
联系方式：13940825088
电子邮箱：cgmeng@dlut.edu.cn
A breathing MOF: direct crystallographic observation of the site-selective C(sp(3))-H functionalization
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论文类型：期刊论文
发表时间：2016-01-01
发表刊物：RSC ADVANCES
收录刊物：SCIE、EI
卷号：6
期号：57
页面范围：51936-51940
ISSN号：2046-2069
摘要：A 3D breathing MOF was synthesized by hierarchical methods for light-driven acceleration of the site-selective C(sp(3))-H activation. The 1D channels of the assembled MOF can encapsulate the reaction substrates via a breathing process that was observed by single-crystal X-ray analyses. The weak interactions between the encapsulated substrate and the photoactive center facilitated the in situ generation of the active alkyl radicals.
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