孟长功

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:中科院金属所

学位:博士

所在单位:化工学院

学科:无机化学

办公地点:大连理工大学化学楼401

联系方式:13940825088

电子邮箱:cgmeng@dlut.edu.cn

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Synthesis of low Si/Al ratio hydroxysodalite from oil shale ash without pretreatment

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论文类型:期刊论文

发表时间:2015-01-01

发表刊物:JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY

收录刊物:SCIE、EI、Scopus

卷号:90

期号:1

页面范围:208-212

ISSN号:0268-2575

关键字:oil shale ash; zeolite; low Si; Al ratio; hydroxysodalite; synthesis

摘要:BACKGROUNDSodalite has been commonly employed as a photochromic material, and low Si/Al ratio sodalite is theoretically suitable for hydrogen storage. Consequently, a green and energy-saving synthetic route towards sodalite from inexpensive sources is highly desirable. Oil shale ash is a fly ash by-product produced from oil shale and has been used to synthesize NaA and zeolite X. In this paper, oil shale ash was selected as raw material to synthesize hydroxysodalite.
   RESULTSThe highly crystallized hydroxysodalite was synthesized by hydrothermal reaction without any pretreatment. The binary crystallization phase diagram was obtained. The optimum reactant molar ratio, hydrothermal reaction temperature, and time are as follows: 10Na(2)O:2SiO(2):75H(2)O, 180 degrees C, 24h. The synthesized hydroxysodalite was further characterized by scanning electron microscopy.
   CONCLUSIONHigh purity and well-crystallized hydroxysodalite was successfully synthesized from oil shale ash without pretreatment. Relatively high molar ratios of Na2O/SiO2 as well as low molar ratios of H2O/Na2O favour the formation of hydroxysodalite. (c) 2014 Society of Chemical Industry