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论文类型：期刊论文

发表时间：2014-10-01

发表刊物：BULLETIN OF MATERIALS SCIENCE

收录刊物：SCIE、EI

卷号：37

期号：6

页面范围：1397-1402

ISSN号：0250-4707

关键字：Amorphous carbon nanotubes; chemical synthesis; structures; oxidation resistance properties

摘要：Tunable amorphous carbon nanotubes (a-CNTs) were successfully synthesized using V3O7 center dot H2O and glucose solution as the starting materials by a novel route for the first time. The as-obtained samples were separately characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), energy-dispersive spectrometer (EDS), elemental analysis (EA), Fourier transform infrared spectroscopy (FT-IR) and Raman spectrum. The results showed that the as-obtained a-CNTs had uniform diameters with outer diameter ranging from 140 to 250 nm and inner diameter about 28 nm on an average, and their length was up to several micrometres. No VO (x) residues remaining in a-CNTs showed the as-obtained a-CNTs with high purity. The as-prepared a-CNTs were a kind of hydrogenated a-CNTs containing both the sp (3)- and sp (2)-type carbons. Furthermore, the thermal stability of the as-obtained a-CNTs in the air atmosphere were investigated by thermo-gravimetric/differential thermal analyser (TG-DTA), revealing that the as-obtained a-CNTs had good thermal stability and oxidation resistance below 300 A degrees C in air.