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论文类型：期刊论文

发表时间：2013-08-01

发表刊物：MICROPOROUS AND MESOPOROUS MATERIALS

收录刊物：SCIE、EI

卷号：176

页面范围：178-185

ISSN号：1387-1811

关键字：Hierarchically porous silica; Fe2O3/HPS hybrids; Photo-Fenton reaction; Visible light; Orange II

摘要：A kind of hierarchically porous silica (HPS) was used as an efficient catalyst carrier to load iron oxide small particles. The obtained Fe2O3/HPS hybrids were characterized by SEM, EDS, XRD, XPS, N-2 adsorption-desorption isotherms, DFT and Hg porosimetry. The catalytic activity of the Fe2O3/HPS was evaluated by the degradation of azo-dye Orange II. The Fe2O3/HPS showed high catalytic activity to the photo-Fenton reaction with vis-light (lambda > 400 nm) irradiation. More than 90% of dye in solution could be degraded. The effects of pH, H2O2 concentration, additive (hydroxylamine hydrochloride), leaching and stability tests were studied. The Fe2O3/HPS could work well in a wider pH range (2.5-8.5) than common homogeneous iron catalyst. Due to the excellent pore structure of HPS, Fe2O3/HPS exhibited much better catalytic ability than normal commercial hematite (Fe2O3) under the same experimental condition. Moreover, Fe2O3/HPS had an ideal stability for the degradation of Orange II after at least ten recycles. (C) 2013 Elsevier Inc. All rights reserved.