个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:中科院金属所
学位:博士
所在单位:化工学院
学科:无机化学
办公地点:大连理工大学化学楼401
联系方式:13940825088
电子邮箱:cgmeng@dlut.edu.cn
Application of graphene for preconcentration and highly sensitive stripping voltammetric analysis of organophosphate pesticide
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论文类型:期刊论文
发表时间:2011-08-12
发表刊物:ANALYTICA CHIMICA ACTA
收录刊物:SCIE、EI、PubMed
卷号:699
期号:2
页面范围:170-176
ISSN号:0003-2670
关键字:Graphene; beta-Cyclodextrin; Solid phase extraction; Differential pulse voltammetry; Methyl parathion
摘要:Electrochemical reduced beta-cyclodextrin dispersed graphene (beta-CD-graphene) was developed as a sorbent for the preconcentration and electrochemical sensing of methyl parathion (MP), a representative nitroaromatic organophosphate pesticide with good redox activity. Benefited from the ultra-large surface area, large delocalized pi-electron system and the superconductivity of beta-CD-graphene, large amount of MP could be extracted on beta-CD-graphene modified electrode via strong pi-pi interaction and exhibited fast accumulation and electron transfer rate. Combined with differential pulse voltammetric analysis, the sensor shows ultra-high sensitivity, good selectivity and fast response. The limit of detection of 0.05 ppb is more than 10 times lower than those obtained from other sorbent based sensors. The method may open up a new possibility for the widespread use of electrochemical sensors for monitoring of ultra-trace OPs. (C) 2011 Elsevier B.V. All rights reserved.