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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：中科院金属所
学位：博士
所在单位：化工学院
学科：无机化学
办公地点：大连理工大学化学楼401
联系方式：13940825088
电子邮箱：cgmeng@dlut.edu.cn
Self-assembly of polyoxometalate clusters and metal-organic coordination fragments into 1D homochiral chains
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论文类型：期刊论文
发表时间：2008-08-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE、Scopus
卷号：11
期号：8
页面范围：914-917
ISSN号：1387-7003
关键字：chirality; polyoxometalate; helical chain
摘要：A pair of enantiornerically pure polyoxometalates, (C4NH7O4)[Na-2(L-C4H8N2O3)(2)(H2O)(g)Zn](2)[CrMo6-H6O24]2 center dot 7H(2)O (L-1), and (C4NH7O4)[Na-2(D-C4H8N2O3)(2)(H2O)(g)Zn](2)[CrMo6H6O24](2) center dot 7H(2)O (D-1), have been synthesized for the first time and characterized by elemental analyses, IR, TG, UV and single crystal Xray diffraction. L-1 and D-1 are enantiomers and crystallize in the chiral space group P2(1)2(1)2. To our best knowledge, they represent the first examples of 1D homochiral polyoxometalate compounds constructed from Anderson-type polyoxoanions. (c) 2008 Elsevier B.V. All rights reserved.