Preparation of Double-Shelled C/SiO2 Hollow Spheres with Enhanced Adsorption Capacity
发布时间：2019-03-09
点击次数：
- 论文类型：
- 期刊论文
- 发表时间：
- 2015-01-21
- 发表刊物：
- INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
- 收录刊物：
- Scopus、EI、SCIE
- 文献类型：
- J
- 卷号：
- 54
- 期号：
- 2
- 页面范围：
- 641-648
- ISSN号：
- 0888-5885
- 摘要：
- In this study, double-shelled C/SiO2 hollow spheres with an outer hydrophilic silica shell and an inner hydrophobic carbon shell were initially prepared by activating a solid silica layer of C/SiO2 aerosol particles. This low-cost preparation technique, which can easily be scaled up, includes a rapid aerosol process and a subsequent dissolution-regrowth process. The large surface area (226.3 m(2)/g), high pore volume (0.51 cm(3)/g), and high mechanical stability of the spheres benefit their high adsorption capacities for methylene blue (MB) and metal ions. The novel spheres show a high adsorption capacity of 171.2 mg/g for MB, which is higher than the adsorption capacity of single-shelled silica hollow spheres (150.0 mg/g). The adsorption efficiency of the hollow spheres remains higher than 95% after five cycles of regeneration. The saturation adsorption values of Pb2+ and Ag+ ions on the hollow spheres were found to be 216.5 and 283.1 mg/g, respectively, which are higher than the corresponding values of 189.8 and 213.4 mg/g on the single-shelled SiO2 spheres. Moreover, the adsorption capacities of the five-times-recycled spheres for Pb2+ and Ag+ ions reached as high as similar to 180 and similar to 245 mg/g, respectively. These results reveal that the outer porous silica layer with a zeta-potential of -37.4 mV makes the main contribution to the excellent adsorption performance of the spheres. In addition to the contribution to the adsorption capacity of the double-shelled hollow spheres, the inner carbon layer plays a crucial role in supporting the outer silica shell and in improving the adsorption efficiency, mechanical stability, and recycling properties of the hollow spheres.
- 第一作者
- Luo, Fan
- 合写作者
- Li, Mo,Zhang, Honglei,Li, Xiangcun,He, Gaohong
- 通讯作者
- Li, XC (reprint author), Dalian Univ Technol, Sch Chem Engn, R&D Ctr Membrane Sci & Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.