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个人信息Personal Information
研究员
博士生导师
硕士生导师
性别：男
毕业院校：北京大学
学位：博士
所在单位：化工学院
学科：无机化学
办公地点：大连理工大学西部校区精细化工国家重点实验室F区208
联系方式：Tel：0411-84986261 email：mengys@dlut.edu.cn
电子邮箱：mengys@dlut.edu.cn
Syntheses, structures and magnetic properties of cyano-bridged (Fe2MII)-M-III (M = Mn, Co and Ni) one-dimensional chains
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论文类型：期刊论文
发表时间：2018-07-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：93
页面范围：144-148
ISSN号：1387-7003
关键字：Cyano-bridged; One-dimensional chain; Building block; Magnetic interaction; Spin glass
摘要：Three novel cyano-bridged one-dimensional chains {[(pzTp)Fe(CN)(3)](2) M(BYI)(2)(CH3OH)(2)center dot 2CH(3)OH](n), (M = Mn (1), Co (2) and Ni (3), BYI = 1, 1'-(1, 4-Butanediyl)bis(imidazole)) composed of cyano-bridged trinuclear (Fe2MII)-M-III units were successfully synthesized based on [(pzTp)Fe(CN)(3)](-) (pzTp = tetrakis(pyrazolyl)borate) unit and bidentate bridging ligand. Structural characterization showed that the three compounds were isostructural. The magnetic interactions could be adjusted by replacing the metal ions with different magnetic anisotropy. Magnetic studies revealed that compound 1 showed antiferromagnetic interaction, while compounds 2 and 3 exhibited ferromagnetic interaction. Interestingly, compound 3 showed the spin glass behavior with the typical slow magnetic relaxation due to the large anisotropy for Ni-II ions and the non-negligible interchain interaction.