|
个人信息Personal Information
研究员
博士生导师
硕士生导师
性别：男
毕业院校：北京大学
学位：博士
所在单位：化工学院
学科：无机化学
办公地点：大连理工大学西部校区精细化工国家重点实验室F区208
联系方式：Tel：0411-84986261 email：mengys@dlut.edu.cn
电子邮箱：mengys@dlut.edu.cn
Spin crossover and structural phase transition in homochiral and heterochiral Fe[(pybox)(2)](2+) complexes
点击次数：
论文类型：期刊论文
发表时间：2019-05-21
发表刊物：DALTON TRANSACTIONS
收录刊物：SCIE、EI
卷号：48
期号：19
页面范围：6323-6327
ISSN号：1477-9226
摘要：Spin crossover and structural phase transition in three pairs of homochiral and heterochiral [Fe(pybox)(2)](2+) diastereomers were investigated through magnetic and crystallographic studies. Herein, we show that the spin transition properties of these compounds are strongly related to the homochiral or heterochiral assembly of the ligands and structural phase transition. Our work demonstrates that chirality is a feasible factor to modulate and influence the molecular geometry and thus the spin-crossover properties of complexes.