胺交联的磺化聚芳醚砜酮荷电膜的制备及微观结构
Release time:2019-03-10
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期刊论文
First Author:
吴雪梅
Correspondence Author:
Wu, X.-M.
Co-author:
贺高红,顾爽,胡正文,姚平经
Date of Publication:
2006-08-20
Journal:
功能材料
Included Journals:
Scopus、EI、PKU、ISTIC、CSCD
Document Type:
J
Volume:
37
Issue:
8
Page Number:
1341-1344
ISSN No.:
1001-9731
Key Words:
磺化聚芳醚砜酮;交联;荷电膜;微观结构;磺酰胺
Abstract:
采用乙二胺(EDA),己二胺(HDA)和对苯二胺(PPD)为交联剂,与磺化杂萘联苯聚芳醚砜酮(SPPESK)反应生成磺酰胺交联键,制备胺交联的磺化杂萘联苯聚芳醚砜酮荷电膜.通过元素分析确定交联程度.采用示差扫描量热,扫描电镜以及应力-应变测试等方法研究交联膜的微观结构.实验结果表明,交联剂的种类、用量以及SPPESK的初始磺化度显著影响体系的相容性,交联剂用量过高会导致交联膜发生微观相分离,影响交联膜的性能.胺交联法制备荷电膜时交联度不宜过高.
Translation or Not:
no
