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Indexed by:期刊论文

Date of Publication:2012-05-01

Journal:Acta crystallographica. Section E, Structure reports online

Included Journals:Scopus、PubMed

Volume:68

Issue:Pt 5

Page Number:o1329

ISSN No.:1600-5368

Abstract:The racemic title compound, C(54)H(38)O(2), consists of two C-linked penta-leno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclo-pentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclo-pentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation.