Release Time:2019-03-11  Hits:

Indexed by: Journal Article

Date of Publication: 2018-01-01

Journal: SUPRAMOLECULAR CHEMISTRY

Included Journals: Scopus、SCIE

Volume: 30

Issue: 1

Page Number: 72-79

ISSN: 1061-0278

Key Words: Cross-linked; supramolecular polymer; pillararene; FRET

Abstract: Cross-linked supramolecular polymers generally show distinct mechanical properties with intriguing functions, which have become one of the hot research topics in recent years. However, the cross-linked supramolecular polymers functionalised with fluorescence resonance energy transfer (FRET) properties have been rarely reported yet. Herein, a new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully. The oligo(p-phenylenevinylene)-linked pillar[5]arene dimer (PA-OPV) functioned as a host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerisation and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV-vis and SEM.
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   A new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully, the oligo(p-phenylenevinylene)-linked pillar[5]arene dimer (PA-OPV) functioned as both host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerization and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV-vis and SEM.