location： Current position: Home >> Scientific Research >> Paper Publications

Highly efficient one-pot synthesis of alpha-free pyrylium salts with tunable fluorescence emission via ring-expanding reaction of triarylcyclopentadienes

Hits:

Indexed by:期刊论文

Date of Publication:2013-06-05

Journal:TETRAHEDRON LETTERS

Included Journals:SCIE、Scopus

Volume:54

Issue:23

Page Number:2967-2971

ISSN No.:0040-4039

Key Words:alpha-Free pyrylium perchlorates; Fluorescence; Crystal structure; DFT calculation

Abstract:A series of a-free pyrylium perchlorates were prepared by one-pot oxidation of substituted cyclopentadiene derivatives in the presence of perchloric acid. A tunable fluorescence with green to red emission in dichloromethane and green to orange emission in the solid state can be achieved by changing the aryl groups on 2- or 4-position of pyrylium ring. Furthermore, single crystal structures and quantum chemistry calculation were conducted to understand the relationship between structures and optical properties. (C) 2013 Elsevier Ltd. All rights reserved.

Pre One:Synthesis, crystal Structures and aggregation-induced emission enhancement of aryl-substituted cyclopentadiene derivatives

Next One:Synthesis, structure and properties of a 3-D Yb(III) metal-organic framework constructed from rod-shaped molecular building blocks
Recommended Ph.D.Supervisor Recommended MA Supervisor Institutional Repository Personal Page

Address: No.2 Linggong Road, Ganjingzi District, Dalian City, Liaoning Province, P.R.C., 116024

Click : times
  • MOBILE Version
    •
    Open time:..
    The Last Update Time:..

    Mobile phone sweep