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A new principle for selective sensing cyanide anions based on 2-hydroxy-naphthaldeazine compound

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Indexed by:期刊论文

Date of Publication:2013-02-01

Journal:SENSORS AND ACTUATORS B-CHEMICAL

Included Journals:SCIE、EI

Volume:177

Page Number:322-326

ISSN No.:0925-4005

Key Words:"Turn-on" fluorescence; 2-Hydroxy-naphthaldeazine; Cyanide anions; Hydrogen bonds; Aggregation-induced emission

Abstract:2-Hydroxy-naphthaldeazine (HNA), synthesized readily via one-step condensation from 3-hydroxy-2-naphthaldehyde and hydrazine monohydrate, behaves as "turn-on" fluorescent sensing of CN-selectively. The sensing mechanism was ascribed to the dual influence of hydrogen bonds and aggregation-induced emission, coming from the interactions of HNA and CN-. The speculation was partially supported by fluorescence emission spectra, UV-vis spectrum, H-1 NMR titration experiments and further particle size analysis. (c) 2012 Elsevier B.V. All rights reserved.

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