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Heterocyclic Radical Mediated Synthesis and Fluorescence Properties of Conjugated Polyene Ketones

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2011-07-15

Journal: ORGANIC LETTERS

Included Journals: PubMed、SCIE、Scopus

Volume: 13

Issue: 14

Page Number: 3608-3611

ISSN: 1523-7060

Abstract: A straightforward route for the preparation of decatetraene diketone derivates is presented. The synthesis has been accomplished by a one-step procedure starting from phenyl-substituted pyrylium perchlorates, and an elaborate heterocyclic alpha-radical mechanism was proposed. This class of molecules displays a crystallization induced emission enhancement property.

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