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Unprecedented Ring Transformation of an alpha,alpha '-Monosubstituted 2,4,5-Triphenylpyrylium Salt with eta(3)-Phosphines Efficient Synthesis of Aryl- and Alkylphosphonium Triphenylcyclopentadienylides

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2010-12-27

Journal: ORGANOMETALLICS

Included Journals: Scopus、SCIE

Volume: 29

Issue: 24

Page Number: 6744-6748

ISSN: 0276-7333

Abstract: The ring transformation of the alpha reactive 2 4 5 triphenylpyrylium salt 1 with eta(3) phosphines to the aryl and alkylphosphonium triphenylcyclopentadienylides 5 is reported The mechanism of this unprecedented transformation might involve tandem conjugate addition and intramolecular Wittig cyclization

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