Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2009-02-01

Journal: INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals: SCIE

Volume: 12

Issue: 2

Page Number: 72-75

ISSN: 1387-7003

Key Words: Coordination polymer; Cadmium(II); Dinuclear building block; Photoluminescence

Abstract: A novel cadmium(II) coordination polymer, [Cd(2)(pzdc)(2)(4,4'-bpy)(2)]center dot 4H(2)O (1) (H(2)pzdc = pyrazine-2,3-dicarboxylic acid; 4,4'-bpy=4,4'-bipyridine), has been synthesized by hydrothermal reaction of Cd(OAC)(2), H(2)pzdc and 4,4'-bpy. Single-crystal X-ray diffraction analysis reveals that 1 constructed from dinuclear building blocks has a three-dimensional (3-D) structure with rob topology. Fluorescent measurement of 1 exhibits strong blue-green emission in the solid state at room temperature, and its framework possess remarkable thermal stability. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.