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室温下纳米Cu3(BTC)2的配位调控合成

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Indexed by:期刊论文

Date of Publication:2012-11-15

Journal:功能材料

Included Journals:EI、PKU、ISTIC、CSCD、Scopus

Volume:43

Issue:21

Page Number:2934-2936,2941

ISSN No.:1001-9731

Key Words:配位聚合物粒子;Cu3(BTC)2;室温;配位调;控合成

Abstract:室温条件下,通过配位调控方法合成了MOF家族中非常重要的成员Cu3(BTC)2(也称为HKUST-1,BTC为均苯三甲酸根)。通过调变反应体系的浓度,成功地获得了50~200nm的Cu2(BTC)2晶体。粉末XRD、TGA测试结果显示产物具有高的结晶度及良好的热稳定性,N2吸附测试结果表明产物具有高的比表面积及孔容积。这种具有高的气体吸附能力的小尺寸粒子在实际过程中将有重要的应用前景。

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